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Evaporative cooling is an essential stage in the creation of Bose-Einstein condensates (BECs) in atomic gases. Recently we suggested [1] that holographic optical traps can be used to increase the evaporation efficiency, leading to larger BECs. In this PhD project you will implement this scheme, which will result in a simplified apparatus for the productions and subsequent manipulation of BECs.

[1] http://pra.aps.org/abstract/PRA/v84/i5/e053410

Transition metal oxides host a wide range of physical properties and functionalities, making them an ideal platform for implementing potential future devices. The aim of this project is to establish novel ways to manipulate the local properties of transition metal oxides by using a scanning tunneling microscope to enable writing device structures at the atomic scale into the surface of the material. To establish the properties of these written device structure, you will first use scanning tunneling spectroscopy, but later also explore possibilities to contact the written structures macroscopically to study transport through these and enable actual device operation. While initial studies will be performed on bulk material, at later stages of the project, thin-film samples grown by reactive oxide molecular beam epitaxy will be used.

In many unconventional superconductors, magnetism and superconductivity occur in close proximity to each other - which is surprising given that they are usually considered mutually exclusive properties of a material. This is also true for the iron pnictide superconductors, where in several materials magnetism and superconductivity appear to coexist from macroscopic measurements. In this project, you will take an atomic scale view at the magnetic order and the superconducting properties using low temperature spin-polarized scanning tunneling microscopy[1]. Combining images of the magnetic order with a characterization of superconductivity from tunneling spectroscopy will allow to establish whether magnetism and superconductivity coexist microscopically, or whether they are really competing. These results provide important benchmarks for theory, and may help to establish an understanding of superconductivity in these materials.

You will be using bespoke low temperature scanning tunneling microscopes, which are installed in a new ultra-low-vibration facility at the University of St Andrews.

[1] Enayat et al., Science 345, 653 (2014)

Defects in two-dimensional materials have recently attracted a lot of interest as they have been shown to have quantum features like single atoms: they have well-defined energy levels, and once excited they can emit one photon at a time. These characteristics are crucial for quantum technologies such as quantum memories and single-photon sources. Coupling the emission from these defects to photonic cavities allows mapping their quantum states to photons which can then be transported and stored, as well as using them as high brightness single-photon sources.

In this project, we are aiming to use carbon defects in hexagonal boron nitride layers as quantum emitters. You will fabricate single-photon sources by placing these defects inside high quality optical Fabry-Perot cavities, and couple their emission to optical fibers. You will study the quantum operation of the device by mapping the photon statistics of the coupled light.

Reference:  Koperski, M. et al. "Midgap radiative centers in carbon-enriched hexagonal boron nitride" PNAS 117, 13214 (2020)

Pulsed dipolar spectroscopy (PDS) forms a sub set of electron paramagnetic resonance (EPR) spectroscopic experiments. PDS exploits the long range dipole-dipole coupling between paramagnetic centres and this allows for the extraction of nanometre scale distances and distributions. The application of these measurements to biomacromolecules, such as nucleic acids and proteins, is a small but important area of the field of structural biology.
 
You will receive training, and therefore become an independent researcher, in:
  1. preparing biomacromolecule samples;
  2. running advanced PDS measurements;
  3. analysing data for its relevance to finding the answers to questions in structural biology.
 
The work will be carried out in fully equipped biological laboratories, and using our state-of-the-art commercial and home-built EPR spectrometers.
 
Given the interdisciplinary nature of this work a scientific background (for example a degree in physics, chemistry or biology) and an enthusiasm for the project are required.
 
You will make full use of the further academic and transferrable skills training on offer, and you will have the option to take part in public engagement and teaching activities.
 
Contact the supervisor Dr Janet Lovett directly for more information, and see https://www.st-andrews.ac.uk/~jel20/

Magnetic resonance is the broad term for techniques that exploit the fundamental and fascinating property of spin. Electron paramagnetic resonance (EPR) spectroscopy is where the spin being used or probed is from a paramagnetic centre, i.e. electron spins. The electron interacts with the environment and the result is that EPR spectroscopy measures details of that environment. 
In this project you will apply existing, and develop bespoke, EPR experiments to a range of open questions about the properties of materials. These materials may be biomolecules and in particular proteins or semiconductors for solar cells depending upon your background and interests. You will work primarily with Dr Janet Lovett, but also collaborate with other researchers. For example, in the St Andrews School of Physics and Astronomy this will include Professor Graham Smith and Dr Lethy Jagadamma.
The EPR equipment is based in the School of Physics and Astronomy and supplemented by equipment in the School of Chemistry. We currently have X-band CW and pulsed spectrometers, Q-band pulsed (with a recent successful grant proposal providing a second soon) and also our home-built world-leading and continuously developed W-band spectrometer, HiPER. You will have access to preparation laboratory space.

Please see https://www.st-andrews.ac.uk/~jel20/.
 

Artificial designer heterostructures of correlated electron systems open up a wide range of exciting possibilities for the creation of new materials. The atomic-layer-by-atomic-layer deposition now achievable in thin films gives a unique potential to manipulate the properties of this still poorly explored new class of materials, ultimately allowing the creation of new phases with properties difficult to attain in bulk compounds [1]. St Andrews has recently opened a new dedicated MBE growth facility with the aim of exploiting the possibilities of such tailored materials.

This new class of materials, however, poses a key challenge to experimentalists interested in such basic thermodynamic properties as specific heat and magnetisation. The extremely low ‘thermal mass’ of such materials compared to bulk systems ultimately requires the development of a new bespoke set of experimental tools for measurement. To bring the paradigm of such fundamental thermodynamic measurements to nanoscale thin films is the key aim of a new research program established at the University of St Andrews of which you will be a key member. During your PhD you will contribute to the development of these new tools with the aim to applying them to the study of designer quantum materials spanning phenomena such as superconductivity, novel (topological) Dirac- and Weyl- systems and (quantum) spin liquids.

[1] J. Mannhart and D. Schlom, Science 327, 1607 (2010).

The aim of this project is to investigate experimentally the influence of broken inversion symmetry on superconductivity in a variety of non-centrosymmetric (NCS) materials. Most crystalline metals have a structure that maps onto itself exactly under inversion of spatial coordinates. Such materials are termed “centrosymmetric” and when they become superconducting, the spatial part of the Cooper pair wavefunction must have a definite parity, i.e. inversion simply multiplies it by ±1. This imposes restrictions also on the spin configuration within the Cooper pair. By contrast, in non-centrosymmetric superconductors where the crystal structure breaks inversion symmetry, such restrictions do not apply. Amongst the properties predicted for non-centrosymmetric superconductors are mixed spin-singlet/spin-triplet pairing, enhanced critical fields and spatially modulated superconducting states. Whilst unusual superconducting properties have been detected in a number of NCS materials, there is relatively little firm experimental evidence linking these to the lack of inversion symmetry; for example only in very few cases has a substantial triplet component of the order parameter been firmly established.

The project will be focused on NCS superconductors where the electronic correlations are weak, since these offer the chance to isolate the role of the broken inversion symmetry. The experiments will focus on using low temperature scanning tunneling microscopy and spectroscopy to establish the structure of the superconducting order parameter and study the influence of defects of different dimensionalities on the superconducting properties.

Many quantum materials exhibit complex magnetic orders, which often are sensitive to external stimuli, such as magnetic field or doping, making them in principle interesting for many technological applications. Characterization of the spatial structure of the magnetic order has mostly been done through Neutron scattering, which however average over a macroscopic sample volume. Spin-polarized scanning tunneling microscope provides real space images of magnetic order at the atomic scale, thereby providing new insights into the spatial structure of the complex magnetic orders. In this project, you will use low temperature scanning tunneling microscopy in a vector magnetic field to characterize the magnetic structure of quantum materials. The studies will aim to establish the surface impact on the magnetic order, knowledge which is critical for technological exploitation and interfacing to other materials, but also to provide a microscopic picture of the magnetic order which will help to identify the dominant contributions to the magnetic interactions in the material. We are in particular interested in metamagnetic phases, where the external magnetic fields can drive phase transitions in the material.

You will be using bespoke low temperature scanning tunneling microscopes, which are installed in a new ultra-low-vibration facility at the University of St Andrews.

[1] Enayat et al., Science 345, 653 (2014).
[2] Singh et al., Phys. Rev. B 91, 161111 (2015).
[3] Trainer, et al., Rev. Sci. Instr. 88, 093705 (2017).

It has been known for a long time that magnetic impurities induce bound states in superconductors [1] but only in recent years it was realised that lining up such states [2] can lead to a twist in the resulting wave function that is known as a changed topological index. The study of such topological states has by now become a highly active field of research. A strong promotor is the rather recent insight that any quantum technology will have to rely on some form of topological states. In this PhD project we will investigate how topological properties appear at interfaces or magnetic structures embedded on superconductors, in a set-up where a strict dimensional decoupling as considered by most approaches is not possible. This will build on our recent work [3]. A particular emphasis will be given to interactions between the states generated by the interaction between the magnetic scatterers and the superconductor, and to particular instabilities that can lead to novel quantum phases.

[1] L. Yu, Acta Phys. Sin. 21, 75 (1965); H. Shiba, Prog. Theor. Phys. 40, 435 (1968); A. I. Rusinov, JETP Lett. 9, 85 (1969).
[2] F. Pientka, L. I. Glazman, and F. von Oppen, Phys. Rev. B 88, 155420 (2013); S. Nadj-Perge, I. K. Drozdov, J. Li, H. Chen, S. Jeon, J. Seo, A. H. MacDonald, B. A. Bernevig, and A. Yazdani, Science 346, 6209 (2014).
[3] C. J. F. Carroll and B. Braunecker, arXiv:1709.06093.