Research areas
Asymmetric synthesis; Homogeneous catalysis; Greener Synthetic methodology; mechanism-led catalyst design.
Selected publications
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An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes
Noonan, G. M., Fuentes García, J. A., Cobley, C. J. & Clarke, M., 5 Mar 2012, In: Angewandte Chemie International Edition. 51, 10, p. 2477-2480 4 p.Research output: Contribution to journal › Article › peer-review
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Open access
High iso aldehyde selectivity in the hydroformylation of short-chain alkenes
Iu, L., Fuentes, J. A., Janka, M., Fontenot, K. J. & Clarke, M. L., 11 Feb 2019, In: Angewandte Chemie International Edition. 58, 7, p. 2120-2124 5 p.Research output: Contribution to journal › Article › peer-review
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Highly Enantioselective Hydroxycarbonylation and Alkoxycarbonylation of Alkenes using Dipalladium Complexes as Precatalysts
Konrad, T. M., Fuentes García, J. A., Slawin, A. M. Z. & Clarke, M., 22 Nov 2010, In: Angewandte Chemie International Edition. 49, 48, p. 9197-9200 4 p.Research output: Contribution to journal › Article › peer-review
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Open access
A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites
Prasad, R. R. R., Dawson, D. M., Cox, P. A., Ashbrook, S. E., Wright, P. A. & Clarke, M. L., 12 Oct 2018, In: Chemistry - A European Journal. 24, 57, p. 15309-15318Research output: Contribution to journal › Article › peer-review
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Open access
Understanding a hydroformylation catalyst that produces branched aldehydes from alkyl alkenes
Dingwall, P., Fuentes, J. A., Crawford, L., Slawin, A. M. Z., Buehl, M. & Clarke, M. L., 8 Nov 2017, In: Journal of the American Chemical Society. 139, 44, p. 15921–15932Research output: Contribution to journal › Article › peer-review
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Open access
Rational design of a facially coordinating P,N,N ligand for manganese-catalysed enantioselective hydrogenation of cyclic ketones
Oates, C. L., Goodfellow, A. S., Bühl, M. & Clarke, M. L., 16 Jan 2023, In: Angewandte Chemie International Edition. 62, 3, 7 p., e202212479.Research output: Contribution to journal › Article › peer-review
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Open access
Manganese catalyzed hydrogenation of enantiomerically pure esters
Widegren, M. B. & Clarke, M. L., 4 May 2018, In: Organic Letters. 20, 9, p. 2654-2658 5 p.Research output: Contribution to journal › Article › peer-review
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Open access
A highly active manganese catalyst for enantioselective ketone and ester hydrogenation
Widegren, M. B., Harkness, G. J., Slawin, A. M. Z., Cordes, D. B. & Clarke, M. L., 8 May 2017, In: Angewandte Chemie International Edition. 56, 21, p. 5825-5828 4 p.Research output: Contribution to journal › Article › peer-review
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Open access
Diastereoselective and branched-aldehyde-selective tandem hydroformylation-hemiaminal formation: synthesis of functionalized piperidines and amino-alcohols
Pittaway, R., Fuentes, J. A. & Clarke, M. L., 2 Jun 2017, In: Organic Letters. 19, 11, p. 2845-2848 4 p.Research output: Contribution to journal › Article › peer-review
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Open access
Rapid asymmetric transfer hydroformylation (ATHF) of disubstituted alkenes using paraformaldehyde as a syngas surrogate
Fuentes García, J. A., Pittaway, R. & Clarke, M., 14 Jul 2015, In: Chemistry - A European Journal. 21, 30, p. 10645-10649Research output: Contribution to journal › Article › peer-review