Dr Andreas Stasch
Reader in Chemistry
Biography
Andreas studied chemistry at the University of Göttingen (Germany) and completed his chemistry diploma (Dipl.-Chem.) in 2000 and his Dr. rer. nat. (PhD) in 2003 under the supervision of Prof. Herbert W. Roesky. He conducted postdoctoral research with Prof. Cameron Jones at Cardiff University (2004-2006), including a stay with Prof. Peter C. Junk at Monash University (Melbourne, Australia) in 2005. Between 2007 and 2016, he held ARC-funded research fellowships (ARF, Future Fellowship) at the School of Chemistry, Monash University. Since 2016, he is a Reader at the School of Chemistry at the University of St Andrews. In 2010 he was awarded the Alan Sargeson Lectureship and in 2014 the Organometallic Chemistry Award by the Royal Australian Chemical Institute. Andreas' group works in numerous areas of molecular inorganic and organometallic chemistry with a focus on the main group elements. Of particular interest are novel low oxidation state compounds, metal hydride complexes, main group organometallics and their stoichiometric and catalytic reactivity.
Teaching
Andreas teaches at both sub-honours and honours level and lectures in CH2501 (Inorganic Chemistry 2), CH3512 (Organometallic Chemistry, Module convenor) and CH4515 (Advanced Main Group Chemistry). Andreas also contributes to the laboratory components of CH1401 (Introductory Inorganic and Physical Chemistry) and CH3521 (Inorganic Chemistry Laboratory), tutorials for various modules, as academic monitor for external placements and various module assessments.
Research areas
We study various research themes in synthetic molecular inorganic and organometallic chemistry with elements from across the periodic table, especially with compounds and complexes of main group elements. Many main group elements are highly Earth abundant, cheap, non-toxic and even biocompatible, and thus are ideally suited for sustainable applications. We discover and investigate fundamentally new compound classes including those with elements in rare oxidation states, unusually bonded fragments and reactive metal hydride species. These generally show novel structures, have unseen properties and as a consequence often show a unique reactivity. We employ these compounds in synthesis, catalysis and towards other applications.
PhD supervision
- Samuel Thompson
- Rochelle Ferns Dsouza
- Huanhuan Dong
- Nikita Demidov
- Connor Bourne
Selected publications
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Open access
Anion stabilised hypercloso-hexaalane Al6H6
Bonyhady, S. J., Collis, D., Holzmann, N., Edwards, A. J., Piltz, R. O., Frenking, G., Stasch, A. & Jones, C., 6 Aug 2018, In: Nature Communications. 9, p. 1-6 6 p., 3079.Research output: Contribution to journal › Article › peer-review
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Open access
Reversible oxidative insertion of a C=C bond into magnesium(I) dimers: generation of highly active 1,2-dimagnesioethane compounds
Boutland, A., Carroll, A., Lamsfus, C., Stasch, A., Maron, L. & Jones, C., 20 Dec 2017, In: Journal of the American Chemical Society. 139, 50, p. 18190-18193Research output: Contribution to journal › Article › peer-review
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Open access
Accessing stable magnesium acyl compounds: reductive cleavage of esters by magnesium(I) dimers
Boutland, A. J., Lamsfus, C. A., Maitland, B., Maron, L., Stasch, A. & Jones, C., 9 Oct 2017, In: Chemistry - A European Journal. 23, 56, p. 14049-14055Research output: Contribution to journal › Article › peer-review
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Open access
Synthesis, characterization, and computational analysis of the dialanate dianion, [H3Al-AlH3]2−: a valence isoelectronic analogue of ethane
Bonyhady, S. J., Holzmann, N., Frenking, G., Stasch, A. & Jones, C., 10 Jul 2017, In: Angewandte Chemie International Edition. 56, 29, p. 8527-8531 5 p.Research output: Contribution to journal › Article › peer-review
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Open access
Heavier group 13 metal(I) heterocycles stabilized by sterically demanding diiminophosphinates: a structurally characterized monomer-dimer pair for gallium
Hawley, A. L., Ohlin, C. A., Fohlmeister, L. & Stasch, A., 5 Jan 2017, In: Chemistry - A European Journal. 23, 2, p. 447-455 9 p.Research output: Contribution to journal › Article › peer-review
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Open access
Ring-shaped phosphinoamido-magnesium-hydride complexes: syntheses, structures, reactivity, and catalysis
Fohlmeister, L. & Stasch, A., 11 Jul 2016, In: Chemistry - A European Journal. 22, 29, p. 10235–10246Research output: Contribution to journal › Article › peer-review
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Activation of CO by hydrogenated magnesium(I) dimers: sterically controlled formation of ethenediolate and cyclopropanetriolate complexes
Lalrempuia, R., Kefalidis, C. E., Bonyhady, S. J., Schwarze, B., Maron, L., Stasch, A. & Jones, C., 22 Jul 2015, In: Journal of the American Chemical Society. 137, 28, p. 8944 - 8947 4 p.Research output: Contribution to journal › Article › peer-review
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A pyrazolate-stabilized sodium hydride complex
Stasch, A., 25 Mar 2015, In: Chemical Communications. 51, 24, p. 5056 - 5058 3 p.Research output: Contribution to journal › Article › peer-review
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Synthesis of a dimeric magnesium(I) compound by an MgI/MgII redox reaction
Stasch, A., 9 Sept 2014, In: Angewandte Chemie International Edition. 53, 38, p. 10200-10203Research output: Contribution to journal › Article › peer-review
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Well-defined, nanometer-sized LiH cluster compounds stabilized by pyrazolate ligands
Stasch, A., 27 Jan 2014, In: Angewandte Chemie International Edition. 53, 5, p. 1338-1341Research output: Contribution to journal › Article › peer-review